海水电沉积作用碳酸钙结晶与珊瑚骨骼晶体的比较     

黄宝威  袁翔城  黄晖  刘胜 《海洋科学》2017,41(7):113-119

电沉积促进珊瑚生长和岸礁修复技术是国际上常采用的生态修复方法,但电沉积技术中电流条件与沉积晶体之间的关系却鲜有研究,关于其形成的电沉积物的晶体结构的报道更是少有。本文探索了在不同电流密度的条件下海水形成碳酸钙晶体的特点,并与珊瑚骨骼晶体进行了对比。本实验设置了300、600、900和1200 m A/m2四组电流密度,在海水中进行5 d电沉积反应,实验后称量了阴极上形成的电沉积物质量,用扫描电子显微镜和X-射线衍射分析了电沉积物中晶体特点并与珊瑚骨骼进行了比较。结果发现,随着电流密度增大,电沉积物质量增加,电流密度为600 m A/m2条件下电沉积物形成的速率与南海的滨珊瑚的生长速率相当。在各个电流密度梯度条件下形成的晶体均与珊瑚骨骼的晶体结构相似。较低电流密度下电沉积物中碳酸钙比例较高。其中,在电流密度为600 m A/m2的条件下,形成的沉积物碳酸钙文石比例最高,和珊瑚骨骼晶体最为接近。本研究为促珊瑚生长的电沉积技术提供了基础数据和理论。  相似文献   

Preparation and Measurement of Cassiterite for Sn Isotope Analysis          下载免费PDF全文

Ryan Mathur  Wayne Powell  Andrea Mason  Linda Godfrey  Junming Yao  Mark E. Baker 《Geostandards and Geoanalytical Research》2017,41(4):701-707

Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO₂, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis.  相似文献   

http://dx.doi.org/10.1016/j.gsf.2016.11.007   总被引：1，自引：1，他引：0  

Tatsuyuki Arai  Shigenori Maruyama 《地学前缘(英文版)》2017,8(2):299-308

Lunar anorthosite is a major rock of the lunar highlands,which formed as a result of plagioclasefloatation in the lunar magma ocean(LMO).Constraints on the sufficient conditions that resulted in the formation of a thick pure anorthosite(mode of plagioclase 95 vol.%) is a key to reveal the early magmatic evolution of the terrestrial planets.To form the pure lunar anorthosite,plagioclase should have separated from the magma ocean with low crystal fraction.Crystal networks of plagioclase and mafic minerals develop when the crystal fraction in the magma(φ) is higher than ca.40-60 vol.%,which inhibit the formation of pure anorthosite.In contrast,when φ is small,the magma ocean is highly turbulent,and plagioclase is likely to become entrained in the turbulent magma rather than separated from the melt.To determine the necessary conditions in which anorthosite forms from the LMO,this study adopted the energy criterion formulated by Solomatov.The composition of melt,temperature,and pressure when plagioclase crystallizes are constrained by using MELTS/pMELTS to calculate the density and viscosity of the melt.When plagioclase starts to crystallize,the Mg~# of melt becomes 0.59 at 1291 C.The density of the melt is smaller than that of plagioclase for P 2.1 kbar(ca.50 km deep),and the critical diameter of plagioclase to separate from the melt becomes larger than the typical crystal diameter of plagioclase(1.8-3 cm).This suggests that plagioclase is likely entrained in the LMO just after the plagioclase starts to crystallize.When the Mg~# of melt becomes 0.54 at 1263 C,the density of melt becomes larger than that of plagioclase even for 0 kbar.When the Mg~# of melt decreases down to 0.46 at 1218 C,the critical diameter of plagioclase to separate from the melt becomes 1.5-2.5 cm,which is nearly equal to the typical plagioclase of the lunar anorthosite.This suggests that plagioclase could separate from the melt.One of the differences between the Earth and the Moon is the presence of water.If the terrestrial magma ocean was saturated with H_2O,plagioclase could not crystallize,and anorthosite could not form.  相似文献   

海洋天然气水合物氢氧同位素分馏初探   总被引：1，自引：0，他引：1  

陈敏  曹志敏  业渝光  刘昌岭 《地球化学》2005,34(6):605-611

天然气水合物的形成会造成氢、氧同位素的分馏.在实验室合成研究中,利用天然海水 [(含 0.03%十二烷基硫酸钠 (SDS)]与甲烷气体反应,通过对水合物生成前后溶液中的 Cl-的质量浓度和氢、氧同位素组成的测定,研究了天然气水合物生成过程中氢、氧同位素的分馏情况.实验证明氢、氧的重同位素易于富集在水合物中,其在天然海水-甲烷体系中的分馏系数分别为 1.018～ 1.036和 1.003 4～ 1.006 3,这一分馏系数稍大于前人在纯水和 NaCl溶液中所测得的分馏系数.  相似文献   

Deep Fractionation of Clinopyroxene in the East Pacific Rise 13°N:Evidence from High MgO MORB and Melt Inclusions     

ZHANG Guoliang  ZENG Zhigang  YIN Xuebo  WANG Xiaoyuan  CHEN Daigeng Key Laboratory of Marine Geology  Environment 《《地质学报》英文版》2009,(2)

Mid-ocean ridge basalts(MORBs)from East Pacific Rise(EPR)13°N are analysed for major and trace elements,both of which show a continuous evolving trend.Positive MgO-Al_2O3 and negative MgO-Sc relationships manifest the cotectic crystallization of plagioclase and olivine,which exist with the presence of plagioclase and olivine phenocrysts and the absence of clinopyroxene phenocrysts.However,the fractionation of clinopyroxene is proven by the positive correlation of MgO and CaO.Thus,MORB samples are believe...  相似文献   

A Comprehensive Method for Fractionating Soil Organic Matter Not Protected and Protected from Decomposition by Physical and Chemical Mechanisms     

César Plaza  José M. Fernández  Engil I. P. Pereira  Alfredo Polo 《洁净——土壤、空气、水》2012,40(2):134-139

The objective of this work was to describe a method for isolating meaningful and measurable soil organic matter (SOM) pools that differ in the mechanisms by which they are protected from decomposition. The proposed method is appropriate for soil C stabilization and sequestration studies. Unlike previous fractionation schemes, this procedure allows free SOM located between aggregates (unprotected C pool) and SOM occluded within both macroaggregates and microaggregates (C weakly and strongly protected by physical mechanisms, respectively) to be recovered separately, freed from the soil mineral matrix and the mineral‐associated SOM pool (C pool protected by chemical mechanisms) and thus well suited to advanced chemical characterization by ¹³C‐NMR. Briefly, free SOM is isolated by an initial density separation. Stable macroaggregates are broken up into stable microaggregates and intra‐macroaggregate SOM, which is then separated by density. Finally, intra‐microaggregate SOM is isolated from mineral‐associated SOM by a third density separation after ultrasonic disruption. The SOM dissolved during the fractionation procedure is also recovered. Results obtained on soil samples with contrasting textures suggested that clay content induces a decrease of the proportion of free organic C and an increase of mineral‐associated organic C content. Free SOM is characterized by a marked presence of undecayed organic material and biologically labile substances, such as carbohydrates and proteins. In contrast, SOM occluded within aggregates, especially within microaggregates, represents a more decomposed fraction, relatively enriched in unsubstituted‐aliphatic material, most probably lipid biopolymers.  相似文献   

Petrogenesis and geochemical characteristics of plagiogranites from Naga Ophiolite Belt,northeast India: Fractional crystallization of MORB-type magma     

《Chemie der Erde / Geochemistry》2017,77(1):183-194

The Naga Ophiolite Belt is a part of the Naga-Arakan-Yoma flysch trough that occurs along the Indo-Myanmar border. It is represented by peridotites, mafic-ultramafic cumulates, mafic volcanics, mafic dykes, plagiogranites, pelagic sediments and minor felsic to intermediate intrusives. Minor plagiogranites, gabbros and thin serpentinite bands occur juxtaposed near Luthur, with the slate-phyllite-metagreywacke sequence (Phokpur Formation) adjacent to the contact. The development of tonalites, trondhjemites and diorites in the oceanic crust, which is grouped as plagiogranites, offers an opportunity to study the process of formation of silicic melts from mafic crust. Plagiogranites from Naga Ophiolite Belt contains moderate SiO₂ (51.81–56.71 wt.%), low K₂O (0.08–1.65 wt.%) and high Na₂O (4.3–5.03 wt.%). The Naga Ophiolite Belt plagiogranites like ocean-ridge granites contain low K₂O, high Na₂O and CaO. The rocks investigated from Naga Ophiolite Belt contain TiO₂ concentrations above the lower limit for fractionated Mid Oceanic Ridge Basalt which is above 1 wt% of TiO₂ and the ternary plots of A (Na₂O + K₂O) F(FeO^T) M(MgO) and TiO₂-K₂O-SiO₂/50 indicate that the plagiogranite are tholeiitic in character and gabbro samples are calc-alkaline in nature. The plagiogranites are enriched in Rb, Ba, Th, U, Nb and Sm against chondrite with negative anomalies on Sr and Zr whereas Y and Yb are depleted to Mid Oceanic Ridge Basalt. The chondrite normalized REE patterns of the plagiogranite display enrichments in LREE (La_N/Sm_N: 2.37–3.62) and flat HREE (Eu/Eu*: 0.90–1.06). The Mid Oceanic Ridge Basalt normalization of gabbro is characterized by strong enrichment of LILE like Ba and Th. The REE pattern is about 50–100 times chondrite with slight enrichment of LREE (La_N/Sm_N = 2.21–3.13) and flat HREE (Eu/Eu*: 0.94–1.19). The major-element and trace element data of the NOB plagiogranites and their intrusive nature with host gabbroic rock suggest that the plagiogranites were produced by fractional crystallization of basaltic parental magmas at Mid Oceanic Ridge.  相似文献   

柴达木北缘东段呼德生镁铁-超镁铁质岩体锆石U-Pb年代学、地球化学及成岩成矿分析   总被引：4，自引：0，他引：4  

钱兵 《地质与勘探》2017,53(5):838-854

呼德生岩体位于柴北缘造山带欧龙布鲁克微陆块东南缘,侵位于古元古代金水口变质岩群中。该岩体从中心到边缘依次出现橄榄岩→辉石岩→辉长岩的岩相分带特征,岩石主要类型有纯橄岩、橄榄二辉岩和辉长岩,各岩石之间多为过渡接触关系,镍铜矿化主要赋存于辉石岩中。锆石LAICP-MS U-Pb年代学研究表明,岩体形成年龄为425.2±5.8Ma,为柴北缘晚志留世-晚泥盆世后造山伸展阶段岩浆作用的产物。岩石镁铁比值(m/f)为2.51~5.37,属于铁质系列基性-超基性岩。各类岩石富集轻稀土元素(LREE)和大离子亲石元素(Ba、Sr、Rb),而亏损高场强元素(Zr、Hf、Nb、Ta)。岩相学、矿物学及岩石地球化学研究表明岩浆在演化过程中发生了一定程度的结晶分异作用和同化混染作用。结合岩体形成年代及区域地质资料,呼德生岩体应形成于大陆边缘伸展阶段,原始岩浆在演化过程中经历了地幔流体的交代作用。通过对岩浆结晶分异程度及同化混染情况等方面的综合评价,认为呼德生岩体具有良好的铜镍硫化物矿床形成条件。  相似文献   

长白山天池火山的岩石矿物学特征——对结晶分异过程和岩浆混合作用的启示     

陈晓雯  魏海泉  杨良锋  陈正全 《地球学报》2017,38(2):177-192

本文对天池火山玄武岩盾,粗面质-碱流质层状锥体以及顶部的粗面质-碱流质碎屑岩类及熔岩的岩石矿物成分做了系统分析,发现在玄武岩类中的主要矿物组合为斜长石、富钙辉石以及富镁橄榄石,而粗面岩-碱流岩类的主要矿物组合为碱性长石、富铁的辉石及橄榄石,并开始出现石英、独居石以及大量的铁钛氧化物,符合结晶分异的演化趋势。同时在玄武岩类及粗面-碱流岩类中均存在不平衡矿物,再结合矿物环带的成分变化、矿物的熔蚀现象及不同特征的岩石条带等,认为天池火山在黑石沟玄武岩、第一、三造锥阶段粗面岩以及千年大喷发的浮岩中均存在岩浆混合作用。根据岩石学及年代学等特征,认为不同时期的玄武质岩浆来自同一地幔源区,经不同程度的结晶分异作用形成,前造锥阶段及造锥阶段的岩石由不同阶段的玄武岩演化而来,全新世的碱流岩类则由造锥阶段粗面岩类演化而来。  相似文献   

热硫化条件下温度对黄铁矿结晶生长的影响   总被引：2，自引：1，他引：1  

寇大明  黄菲  杨大勇  李光禄  王岳松  谭伟  郭耀宇 《吉林大学学报(地球科学版)》2010,40(1):104-108

模拟天然黄铁矿形成条件和基本过程,利用真空管式炉实验设备,通过热硫化法在250～410℃反应,实验考察不同温度条件下黄铁矿的结晶生长情况。运用扫描电镜、X射线粉晶衍射分析等手段,对实验产物形貌、物相结构特点等进行测试分析。结果表明：250～410℃时均可形成黄铁矿,但250～280℃时黄铁矿结晶程度较差;310～340℃时,可生长出部分晶面;360℃时黄铁矿生长成较为完好的晶体;380℃时黄铁矿结晶成立方体、八面体等自形晶;410℃时可形成结晶好、成分单一的黄铁矿。  相似文献